Journal of Liaoning Petrochemical University
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Preparation of Pt/γ⁃Al 2O 3 by Rotary Microemulsion Method for Catalytic Oxidation of Methanol
Wei GAO, Xin ZENG, Jinxiao LI, Chunhua YANG, Yaqi WANG, Sumin LI, Shuang LÜ, Liwei PAN
Abstract95)   HTML6)    PDF (1193KB)(57)      

In the methanol autothermal reforming reaction, the required heat is provided by the methanol oxidation reaction, so the activity of the methanol oxidation catalyst directly affects the yield of hydrogen. Pt/γ?Al2O3 catalysts have attracted wide attention because of its high reactivity, but their stability is poor, and the Pt activity center is easy to agglomerate. In order to solve the above problems, Pt/γ?Al2O3 catalysts were prepared by rotary microemulsion, and Pt/γ?Al2O3 catalysts were characterized by BET, XRD and other methods, and the effects of cyclohexane mass fraction, mass ratio of PEG?600 and n?butanol on the oxidation activity of methanol were investigated. The results show that the microemulsion method could improve the dispersion and utilization rate of the active components. By changing the mass fraction of cyclohexane and the mass ratio of PEG?600 to n?butanol, the active component Pt can be uniformly and firmly loaded on γ?Al2O3, and the sintering resistance of the catalyst can be improved. The Pt/γ?Al2O3 catalyst prepared under the condition of cyclohexane mass fraction of 50% and the mass ratio of PEG?600 to n?butanol is 3∶7, and the catalytic activity of methanol oxidation can reach 88%.

2023, 43 (6): 44-47. DOI: 10.12422/j.issn.1672-6952.2023.06.007
A Review of Research on Hydrogen Production Technology for Hydrogen Powered Ships
Bin WANG, Rensheng SONG, Guogang YANG, Sumin LI, Yulong LIU, Liwei PAN, Jing ZHANG
Abstract122)   HTML17)    PDF (2616KB)(91)      

In the context of the shipping industry emission reduction target set by the International Maritime Organization and based on the current situation of carbon reduction in the shipping industry, this paper introduces the development history and emission reduction advantages of hydrogen powered ships, analyzes the hydrogen storage methods of hydrogen powered ships at home and abroad and the safety risks of hydrogen energy onboard, and compares the technical advantages and onboard feasibility of various Marine hydrogen storage methods. It is concluded that the hydrogen production technology of shipboard methanol steam reforming is of great significance to solve the hydrogen safety problem of hydrogen?powered ships. At last, the problems faced in developing hydrogen?powered ships with shipboard hydrogen production units are put forward.

2023, 43 (6): 22-29. DOI: 10.12422/j.issn.1672-6952.2023.06.004
Research Progress of Non⁃Homogeneous Ozone Oxidation Catalysts in Water Treatment
Jianwei Song, Jing Zhang, Kaiwen Tan, Liwei Pan, Hexiang Zhong
Abstract445)   HTML    PDF (1022KB)(317)      

Ozone is a clean and strong oxidant, which has been widely used in the degrading of organic pollutants. However, the ozone oxidation process alone is not ideal for the treatment of difficult?to?degrade organic pollutants in water. Therefore, ozone catalytic oxidation technology came into being, and the selection of catalyst is the key factor to determine its degradation effect. Based on the various types of catalysts, the mechanism of metal oxides, carbon?based materials and supported composite catalysts for the catalytic oxidation treatment of water pollutants by ozone was reviewed. The existing problems and the main problems that need to be solved at present were analyzed to provide theoretical basis and reference for the research and development of suitable catalysts.

2022, 42 (3): 8-13. DOI: 10.3969/j.issn.1672-6952.2022.03.002
Review of Copper⁃Based Catalysts for Electrocatalytic Reduction of Carbon Dioxide
Guohua Diao, Liwei Pan, Lin Fan, Xinyu Han, Hexiang Zhong
Abstract3040)   HTML    PDF (855KB)(494)      

With the rapid economic development, the demand for energy continues to increase, and the emission of CO2 gas keep growing. The electrochemical reduction of carbon dioxide (ERC) to fuel and chemicals is an effective way to realize the conversion and utilization of CO2 as well as the storage of renewable energy. Cu?based catalysts are one of the materials which can directly reduce CO2 to high value?added chemicals(such as hydrocarbons) with high efficiency. Thus, the Cu?based catalysts have been one of the research focus of ERC technology research. The main research progress of Cu?based catalysts for ERC technology in recent years is reviewed. Firstly, reaction principle of ERC and the technology challenge are summarized, and then the cooperative control strategy for the structure and composition of copper?based catalysts is discussed for monometallic copper?based catalysts, polymetallic copper?based catalysts, copper oxide and oxide?derived copper catalysts, and copper?organic composite catalysts. In addition, research progress and unsolved problems of Cu?based catalysts are also summarized. Finally, the future trend these catalysts is also prospected.

2021, 41 (4): 1-8. DOI: 10.3969/j.issn.1672-6952.2021.04.001